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| Registros recuperados : 21 | |
| 2. |  | GUALBERTO, G. F.; SILVA, G. F. da; CRUZ, J. C. da; ALMEIDA, F. L. de. Amplificação e clonagem do gene sox9 em tambaqui (Colossoma macropomum). In: CONGRESSO BRASILEIRO DE AQUICULTURA DE ESPÉCIES NATIVAS, 4., 2013, Belém, PA. [Resumos]. [Belém, PA: s.n.], 2013.| Biblioteca(s): Embrapa Amazônia Ocidental. |
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| 4. | | GUALBERTO, G. F.; SILVA, G. F. da; CRUZ, J. C. da; ALMEIDA, F. L. de. Desenvolvimento de primers degenerados para genes envolvidos na diferenciação sexual testicular em peixes. In: CONGRESSO BRASILEIRO DE AQUICULTURA DE ESPÉCIES NATIVAS, 4., 2013, Belém, PA. [Resumos]. [Belém, PA: s.n.], 2013.| Biblioteca(s): Embrapa Amazônia Ocidental. |
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| 9. | | FARIA, A. L. A.; CENTURION, H. A.; TORRES, J. A.; GONÇALVES, R. V.; RIBEIRO, L. S.; RIBEIRO, C.; CRUZ, J. C. da; NOGUEIRA, F. G. E. Enhancing Nb2O5 activity for CO2 photoreduction through Cu nanoparticles cocatalyst deposited by DC-magnetron sputtering. Journal of CO2 Utilization, v. 53, 101739, 2021. 1 - 8| Biblioteca(s): Embrapa Instrumentação. |
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| 10. | | PEIXOTO, J. C.; NOGUEIRA, A. E.; DIAS, A.; TORRES, J. A.; CRUZ, J. C. da; RIBEIRO, C.; SIQUEIRA, K. P. F. Experimental evaluation of the activity and selectivity of pure MnWO4 and doped with rare earth ions in the CO2 photoreduction process. Materials Research Bulletin,, v. 153, 111912, 2022. 1 - 10| Biblioteca(s): Embrapa Instrumentação. |
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| 11. | | ANGELO, P. C. da S.; CHAVES, F. C. M.; BIZZO, H. R.; XAVIER, J. J. B. N.; CRUZ, J. C. da; LIRA, M. P. S. Genetic diversity in sacaca (Croton cajucara Benth.) accessed by RAPD markers. Revista Brasileira de Plantas Medicinais, Botucatu, v. 8, n. esp., p. 18-22, 2006.| Biblioteca(s): Embrapa Amazônia Ocidental. |
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| 12. | | ANGELO, P. C. da S.; CHAVES, F. C. M.; BIZZO, H. R.; XAVIER, J. J. B. N.; CRUZ, J. C. da. Diversidade genética em sacaca: agrupamento de plantas dos morfotipos vermelha e branca do Banco de Germoplasma de Croton da Embrapa Amazônia Ocidental. In: JORNADA AMAZONENSE DE PLANTAS MEDICINAIS, 1., 2005, Manaus. Situação atual, integração e perspectivas no Estado do Amazonas. Manaus: FUCAPI: UFAM: INPA: Embrapa Amazônia Ocidental, 2005. 1 CD-ROM.| Biblioteca(s): Embrapa Amazônia Ocidental. |
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| 15. | | GUALBERTO, G. F.; CATARINO, A. de M.; SOUSA, T. F.; CRUZ, J. C. da; HANADA, R. E.; CANIATO, F. F.; SILVA, G. F. da. Pseudopestalotiopsis gilvanii sp. nov. and Neopestalotiopsis formicarum leaves spot pathogens from guarana plant: a new threat to global tropical hosts. Phytotaxa, v. 489, n. 2, p. 121-139, 2021.| Biblioteca(s): Embrapa Amazônia Ocidental. |
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| 16. | | SOTERO, T. do P.; SOUZA, M. G. de; ANGELO, P. C. da S.; BICHARA, K. P. de A.; CRUZ, J. C. da. Variabilidade genética de isolados de Crinipellis perniciosa. In: JORNADA DE INICIAÇÃO CIENTÍFICA DA EMBRAPA AMAZÔNIA OCIDENTAL, 1., 2004, Manaus. Anais... Manaus: Embrapa Amazônia Ocidental, 2004. p. 37-40. (Embrapa Amazônia Ocidental. Documentos, 35).| Biblioteca(s): Embrapa Amazônia Ocidental. |
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| 17. | | CANIATO, M. M.; CATARINO, A. de M.; SOUSA, T. F.; SILVA, G. F. da; BICHARA, K. P. de A.; CRUZ, J. C. da; ASSIS, L. A. G. de; HANADA, R. E. Diversity of bacterial strains in biochar-enhanced Amazon soil and their potential for growth promotion and biological disease control in tomato. Acta Amazônica, v. 50, n. 4, p. 278-288, Oct./Dec. 2020. Título em Português: Diversidade de isolados bacterianos em solo amazônico enriquecido com biocarvão e seu potencial para a promoção de crescimento e controle biológico de doenças em tomate.| Biblioteca(s): Embrapa Amazônia Ocidental. |
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| 18. | | SILVA-FILHO, F. A. da; SOUZA, M. M. M. de; REZENDE, G. O.; SILVA, F. M. A. da; CRUZ, J. C. da; SILVA, G. F. da; SOUZA, A. D. L. de; SOUZA, A. Q. L. de. Screening of alkaloid-producing endophytic Penicillium strains from Amazon medicinal plants by Electrospray Ionization Mass Spectrometry (ESI-MS) and Principal Component Analysis (PCA). Journal of the Brazilian Chemical Society, v. 32, n. 9, p. 1832-1839, 2021.| Biblioteca(s): Embrapa Amazônia Ocidental. |
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| 19. | | ANGELO, P. C. da S.; CHAVES, F. C. M.; BIZZO, H. R.; XAVIER, J. J. B. N.; CRUZ, J. C. da; COUTO, H. A. R. do; MORAIS, I. da S. de; JANAÍNA, K. G. M.; FARIAS, S. M. de. RAPD como técnica para a distinção entre acessos de sacaca vermelha (Croton cajuçara Benth.) do Banco de Germoplasma da Embrapa Amazônia Ocidental. In: JORNADA AMAZONENSE DE PLANTAS MEDICINAIS, 1., 2005, Manaus. Situação atual, integração e perspectivas no Estado do Amazonas. Manaus: FUCAPI: UFAM: INPA: Embrapa Amazônia Ocidental, 2005. 1 CD-ROM.| Biblioteca(s): Embrapa Amazônia Ocidental. |
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| 20. | | FERNANDES, K. R. P.; SOUZA, A. Q. L. de; SANTOS, L. A. dos; NOGUEIRA, F. C. S.; EVARISTO, J. A. M.; CARNEIRO, G. R. A.; SILVA, G. F. da; CRUZ, J. C. da; SOUSA, T. F.; SILVA, S. R. S. da; BASTOS, I. dos S.; ORLANDI, P. P.; SOUZA, A. D. L. de. Asperelines produced by the endophytic fungus Trichoderma asperelloides from the aquatic plant Victoria amazonica. Revista Brasileira de Farmacognosia, v. 31, p. 667-675, 2021.| Biblioteca(s): Embrapa Amazônia Ocidental. |
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| Registros recuperados : 21 | |
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Registro Completo
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Biblioteca(s): |
Embrapa Instrumentação. |
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Data corrente: |
05/10/2023 |
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Data da última atualização: |
15/01/2024 |
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Tipo da produção científica: |
Orientação de Tese de Pós-Graduação |
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Autoria: |
CRUZ, J. C. da. |
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Título: |
PHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE. |
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Ano de publicação: |
2023 |
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Fonte/Imprenta: |
2023. Tese ( Doutorado em Ciências, área de concentração: físico-química), Universidade Federal de São Carlos, Programa de Pós-Graduação em Química, São Carlos-SP. |
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Páginas: |
98 p. |
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Idioma: |
Inglês |
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Notas: |
Orientador: Caue Ribeiro de Oliveira
Coorientadora: Elaine Cristina Paris |
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Conteúdo: |
ABSTRACT PHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE. The CH4 partial oxidation into value-added chemicals by solar means has been discussed as alternative for emission abatement, a fundamental topic for sustainable production with lower global warming gas emissions in future. So far, various semiconductor photocatalysts have been developed. However, the understanding of the main factors influencing photocatalysts' activities on controlled oxidation of methane to methanol is still an issue, especially due to methane overoxidation to CO2. Thus, we propose that the semiconductor must have a valence band (VB) favorable to produce hydroxyl radicals (?OH) and a conduction band (CB) not advantageous to superoxide radical (O2). Furthermore, the concentration of the hydroxyl radicals is fundamental and should be fine-tuned for selectively oxidize methane. O2 also is the key oxidant for process control, since O2 may scavenging methyl radicals (?CH3) that further react with ?OH to form methanol. Our results showed that the required band edge positions for photocatalysts (e.g., Bi2O3) seems correct to obtain significant amounts of desirable chemical products, taking as main products methanol (3700 μmol g-1 ) and acetic acid acetic acid (~2036 μmol g -1 h -1 ) from pure CH4 at room temperature and atmospheric pressure. Moreover, longer hydrocarbons (e.g., ethanol and acetone) could be produced depending on the reaction condition. ESR experiments proved the formation of ?CH3 and ?OH, and isotope labeling experiment with 13CH4 asthe reactant also was conducted, confirming that CH3OH comes from CH4 photooxidation.Another sustainable route to control the CH4 oxidation driven by chloride intermediates in solution using Bismuth-based semiconductors excited in visible light was investigated. BiOCl, a perovskite layered material, exhibited promising photocatalytic performance for methane conversion to methanol (1300 µmol g-1 ), acetic acid (435 µmol g-1 ), and ethanol (57 µmol g-1 ) without foreign radicals to control the reaction. Our findings are significant to new level of understanding in methane?s efficient partial photooxidation, which opens a way to control competitive reactions by appropriate band edge positions in photocatalysts to greater selectivity and avoid its overoxidation to CO2 MenosABSTRACT PHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE. The CH4 partial oxidation into value-added chemicals by solar means has been discussed as alternative for emission abatement, a fundamental topic for sustainable production with lower global warming gas emissions in future. So far, various semiconductor photocatalysts have been developed. However, the understanding of the main factors influencing photocatalysts' activities on controlled oxidation of methane to methanol is still an issue, especially due to methane overoxidation to CO2. Thus, we propose that the semiconductor must have a valence band (VB) favorable to produce hydroxyl radicals (?OH) and a conduction band (CB) not advantageous to superoxide radical (O2). Furthermore, the concentration of the hydroxyl radicals is fundamental and should be fine-tuned for selectively oxidize methane. O2 also is the key oxidant for process control, since O2 may scavenging methyl radicals (?CH3) that further react with ?OH to form methanol. Our results showed that the required band edge positions for photocatalysts (e.g., Bi2O3) seems correct to obtain significant amounts of desirable chemical products, taking as main products methanol (3700 μmol g-1 ) and acetic acid acetic acid (~2036 μmol g -1 h -1 ) from pure CH4 at room temperature and atmospheric pressure. Moreover, longer hydrocarbons (e.g., ethanol and acetone) could be produced depending on the reaction condition. ESR experiments proved the formatio... Mostrar Tudo |
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Palavras-Chave: |
Superoxidação em CO2. |
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Categoria do assunto: |
-- |
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URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/doc/1157124/1/TS-PHOTOCATALYTIC-CONTROLLED-OXIDATION.pdf
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Marc: |
LEADER 02955nam a2200145 a 4500
001 2157124
005 2024-01-15
008 2023 bl uuuu m 00u1 u #d
100 1 $aCRUZ, J. C. da
245 $aPHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE.$h[electronic resource]
260 $a2023. Tese ( Doutorado em Ciências, área de concentração: físico-química), Universidade Federal de São Carlos, Programa de Pós-Graduação em Química, São Carlos-SP.$c2023
300 $a98 p.
500 $aOrientador: Caue Ribeiro de Oliveira Coorientadora: Elaine Cristina Paris
520 $aABSTRACT PHOTOCATALYTIC CONTROLLED OXIDATION REACTION OF METHANE. The CH4 partial oxidation into value-added chemicals by solar means has been discussed as alternative for emission abatement, a fundamental topic for sustainable production with lower global warming gas emissions in future. So far, various semiconductor photocatalysts have been developed. However, the understanding of the main factors influencing photocatalysts' activities on controlled oxidation of methane to methanol is still an issue, especially due to methane overoxidation to CO2. Thus, we propose that the semiconductor must have a valence band (VB) favorable to produce hydroxyl radicals (?OH) and a conduction band (CB) not advantageous to superoxide radical (O2). Furthermore, the concentration of the hydroxyl radicals is fundamental and should be fine-tuned for selectively oxidize methane. O2 also is the key oxidant for process control, since O2 may scavenging methyl radicals (?CH3) that further react with ?OH to form methanol. Our results showed that the required band edge positions for photocatalysts (e.g., Bi2O3) seems correct to obtain significant amounts of desirable chemical products, taking as main products methanol (3700 μmol g-1 ) and acetic acid acetic acid (~2036 μmol g -1 h -1 ) from pure CH4 at room temperature and atmospheric pressure. Moreover, longer hydrocarbons (e.g., ethanol and acetone) could be produced depending on the reaction condition. ESR experiments proved the formation of ?CH3 and ?OH, and isotope labeling experiment with 13CH4 asthe reactant also was conducted, confirming that CH3OH comes from CH4 photooxidation.Another sustainable route to control the CH4 oxidation driven by chloride intermediates in solution using Bismuth-based semiconductors excited in visible light was investigated. BiOCl, a perovskite layered material, exhibited promising photocatalytic performance for methane conversion to methanol (1300 µmol g-1 ), acetic acid (435 µmol g-1 ), and ethanol (57 µmol g-1 ) without foreign radicals to control the reaction. Our findings are significant to new level of understanding in methane?s efficient partial photooxidation, which opens a way to control competitive reactions by appropriate band edge positions in photocatalysts to greater selectivity and avoid its overoxidation to CO2
653 $aSuperoxidação em CO2
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